LHTCS-305 Zinc Oxide Desulfurization Catalyst
1. Product Introduction
LHTCS-305 Zinc Oxide Desulfurization catalyst is applicable to desulfurization of residue cracking gases or syngas and purification of feed gases for organic synthesis processes. It is suitable for both higher (350--408°C) and lower (150--210°C) temperature use. It can convert some simpler organic sulfur while absorbing inorganic sulfur in gas stream.
Main reaction of the desulfurization process is as follows:
(1) Reaction of zinc oxide with hydrogen sulfide
H2S+ZnO=ZnS+H2O
(2) Reaction of zinc oxide with some simpler sulfur compounds in two possible ways:
a. Organic sulfur compounds, catalyzed by zinc oxide, react with hydrogen to form hydrogen sulfide:
CS2 + 4H2 = CH4 + 2H2S
C2H5SH + H2 = C2H6 + H2S
Then hydrogen sulfide is absorbed by zinc oxide
H2S+ZnO=ZnS+H2O
b. Zinc oxide reacts directly with organic sulfur compounds
COS + ZnO = ZnS + CO2
LHTCS-305 is an ideal desulfurization adsorbent for deep purification cases, especially those at higher temperature (350--400°C).
2. Physical Properties
Appearance
Gray white extrudates
Diameter, mm
4±0.2
Length, mm
4-10
ZnO, wt%
=90
Bulk density, kg/L
1.10~1.25
3. Quality Standard
Crushing strength, N/cm
=40
Surface area, m2/g
=30
Loss on attrition, %
=5
Loss on ignition
(The original base burning
for 2 hr at 500?) ,wt%
=2
Breakthrough sulfur capacity,
wt%
=28(350°C)
=15(220°C)
=10(200°C)
4. Normal Operation Condition
Feedstock : synthesis gas , oil field gas, natural gas, coal gas. It can treat gas stream with inorganic sulfur as high as 2-3g/m3 with satisfactory purification degree. It can also purify gas stream with up to 20mg/m3 of such simpler organic sulfur as COS to less than 0.1ppm.
Normal operation condition is as follows:
Pressure, MPa
ambient to 4.0
Temperature, °C
150-400
Space velocity, h-1
1000-2000(gas)
Sulfur in feed gas, mg/m3
1-20 (=200°C)
20-100 (=250°C)
Sulfur in treated stream, ppm
max0.1
Saturation sulfur capacity, wt%
min30(400°C)
LHTCS-305 Zinc Oxide Desulfurization Catal...
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